It is made up of a series of hic hydrogen induced cracking cracks that are stacked perpendicularly in the direction of through wall cracks and driven by high residual or applied stresses. Gas phase water needs to be there as well even in a trace amount. Nace mr0175 and mr0103 standards metals for sulfide stress. Sulfide stress cracking ssc vs hydrogen induced cracking. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. In the usa, nace international issues a periodically updated standard mr0175 nace 2000 for materials selection for such service. Wet hydrogen sulfide h2s cracking inspectioneering. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process. Stress corrosion cracking behavior of nickel base alloys. It is applied if the hydrogen sulfide content of the gas phase exceeds a partial pressure of 3.
Stress corrosion crack scc is a crack which may be intergranular or transgranular depending on the material, resulting from the combined action of corrosion and stress, either external applied or internal residual. A high incidence of sulfide induced hic has resulted in the coining of the term sulfide stress corrosion cracking ssc. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. It addresses hydrogeninduced cracking of steel weldments, sensitization and subsequent intergranular corrosion of stainless steel weldments, sulfide stress cracking of pipeline steel weldments, microbiologically induced corrosion of weldments, and stress corrosion cracking of weldments. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas. The influence of free stream turbulence on the local heat transfer from cylinders seban, r.
The authors conducted extensive analyses to explore the effects of metallurgical factors on the resistance of line pipe steels to hydrogen induced cracking hic and sulfide stress cracking. Environmental cracking refers to the brittle fracture of a normally ductile material in which the corrosive effect of the environment is a causative factor. Sulfide stress cracking mostly occurs in very highly acidic environments. Processes or conditions involving wet hydrogen sulfide, i. Other types of material damage include hydrogen blistering, hydrogeninduced cracking hic, and stressoriented hydrogeninduced cracking sohic, which are not addressed by this standard. Corrosion can also happen when metals like steel are placed under too much stress causing the material to crack. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Unfortunately, all three phenomena reveal themselves in the same type of crack, and it is often difficult to identify the cause. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Basics of sulfide stress cracking ssc and stress corrosion cracking scc ssc and scc are cracking processes that develop in the presence of water, corrosion and surface tensile stress. Sulfide stress cracking an overview sciencedirect topics. Additionally, if h2s is present, resistance to sulfide stress cracking may be required, depending also on other environmental conditions. Even without h2s, contents of co2, chlorides, and high temperatures and pressures can represent a risk of high corrosion rates.
Corrosion of iron the most common type of iron corrosion occurs when it is exposed to oxygen and the presence of water, which creates a. Sulfide stress cracking of pipelinecase history onepetro. Think of it as nace mr0175 for petroleum refineries. However, the time required for crack initia tion is strongly dependent on a wide variety of pa rameters, such as surface finish. In this environment, not only is hydrogen sulfide stress cracking a concern, but the presence of brine or salt water introduces the additional. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by.
Definition of sulfide stress cracking iadc lexicon. The sulfide stress cracking fracture toughness is primarily a function of alloy composition and microstructure. There are a number of approaches that can be used to prevent or at least delay the onset of scc. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Cracking of metal involving corrosion and tensile stress residual andor applied in the presence of water and h2s. An industry value that has been developed is nace mr01. Sulfide stress cracking of highstrength steels is a problem in handling sour hydrogen sulfide containing crude oil or natural gas. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides.
In order for heat affected zone cracking to occur, three. Centerline cracking is the result of one of the following phenomena. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular concern to the oil and gas industry 3. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Sulphide stress corrosion cracking how is sulphide stress. Producing wet sour gas presents some of the toughest technical challenges in the oil and gas business. Dunlop named this type of eac sulfide corrosion stress cracking scsc, which is now an obsolete term. As we know that both form of cracking are due to the absorption of atomic hydrogen. Iso 151563 will set new restrictions on uns s174000 174ph october 22, 2014 by mariano.
Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches. Stress corrosion cracking facts and how to reduce the risk. Chapter 9 stress corrosion cracking chapter contents 9. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. The authors conducted extensive analyses to explore the effects of metallurgical factors on the resistance of line pipe steels to hydrogen induced cracking hic and sulfide stress cracking ssc. Prevention of sulfide stress cracking in sourcondensate well equipment mcguire, w. Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Nace mr0175 was originally created to cover sulfide stress cracking in the oil and gas production industry.
It should not be confused with the term stress corrosion cracking which is an anodic. Sulfide stress cracking nace mr01752002, mr0175iso. Mar 03, 2014 environmental cracking or environmentally assisted cracking eac is the cracking of a material wherein an interaction with its environment is a causative factor in conjunction with tensile stress authors note. As seen in figure 1, cracking was observed only on the tension side of ubend samples. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc.
Once the sulfide gasses make their way to the surface, they react with air and moisture to form sulfuric acid which is highly aggressive to both metal and nonmetal materials. Api spec 6a, specification for wellhead and christmas tree equipment, twentieth edition, october 2010 addendum november 2012. Oct 24, 20 sulfide stress cracking resistant drill pipe addresses h2s challenges. Highstrength steel steel to be under stress residual or externally applied. Chloride stress corrosion cracking in austenitic stainless steel, parrot and pitts, harpur hill, 2011. It is a form of hydrogenrelated cracking and can have two distinct morphologies.
Jul 25, 2017 sulfide stress cracking meaning sulfide s. Environmental cracking is a broad term that includes corrosion fatigue, hightemperature hydrogen attack, hydrogen blistering, hydrogen embrittlement. The nace mr0175 standard, also known as iso15156 international standard, was developed for the prevention of sulfide stress cracking due to h2s in oil and gas production systems. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. This mode of attack is termed stress corrosion cracking scc.
Tcr engineering mumbai corrosion testing, nace, astm. Biological corrosion can typically be seen in the form of pitting or sulfide stress cracking on the inner walls of piping systems. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. How to make an arizona penny can alcohol stove duration. Sulfide stress cracking how is sulfide stress cracking. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Stress corrosion cracking definition and meaning collins. Wet h 2 s cracking can occur in susceptible steels exposed to aqueous environments containing hydrogen sulfide. Pdf sulfide stress corrosion cracking and hydrogen. The most common type of iron corrosion occurs when it is exposed to oxygen and the presence of water, which creates a red iron oxide commonly called rust. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen.
Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. Sulfide stress cracking definition sulfide stress cracking explanation. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. It is a progressive type of failure that produces cracking at stress levels that are well below the materials tensile strength. Is sulfide stress cracking an anodic or a cathodic process. Stress corrosion cracking is a type of corrosion that can happen when a stress is present. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. The nace mr0175 standards metals for sulfide stress cracking and stress corrosion cracking resistance in sour oilfield environments. Stress corrosion cracking facts and how to reduce the.
H 2 s can cause sulfide stress cracking of stainless steels. Nace mr01032012, materials resistant to sulfide stress cracking in corrosive petroleum refining environments, nace international, 2012. In an ideal world a stress corrosion cracking control strategy will start operating at the design stage, and will focus on the selection of material, the limitation of stress and the control of the environment. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Environmental cracking is a broad term that includes corrosion fatigue, hightemperature hydrogen attack, hydrogen blistering, hydrogen embrittlement, liquid metal embrittlement, season cracking, caustic embrittlement, stress corrosion cracking, stepwise cracking, sulfide corrosion cracking and sulfide stress cracking. Note ssc is a form of hydrogen stress cracking hsc and involves embrittlement of the metal by atomic hydrogen that is produced by acid corrosion on the metal surface. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. Hydrogen uptake is promoted in the presence of sulfides. Sulfide stress cracking nace mr01752002, mr0175iso 15156. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism.
Pdf sulfide stress corrosion cracking and hydrogen induced. Because this cracking occurs after the steel has cooled below approximately 400f, it can be called cold cracking, and because it is associated with hydrogen, it is also called hydrogen assisted cracking. The presence of flaws that concentrate stress or crevices that alter. Historically, for the refining process, the mr0175 standard was used as a guideline for choosing suitable materials. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. The original 1997 cepa stress corrosion cracking recommended practices hereafter referred to as the practices were prepared and made public by cepa in response to a the national energy board of canadas public inquiry mh295 into the problem of stress corrosion cracking scc in oil and gas pipelines. Corrosion in the oil industry denis brondel montrouge, france randy edwards columbus, ohio, usa andrew hayman. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. Material selection for sour service environment pipeline.
Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide. Closure to discussions of prevention of sulfidestress cracking in sourcondensate well equipment 1960, asme j. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials when the. Sohic is a type of cracking that can easily lead to failure and needs to be mitigated. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. Low alloy steels, stress corrosion cracking, sulfide stress cracking tagged with. Standard material requirements materials resistant to. Nace mr01752015, petroleum and natural gas industries. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible. Stress oriented hydrogen induced cracking sohic is a common, insidious form of wet h2s cracking.
H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. Cracking of metallic materials due to exposure to fluid containing hydrogen sulfide. Cracking of metallic materials due to exposure to hydrogen sulfide containing fluids. Nace mr0103 is a new standard entitled materials resistant to sulfide stress cracking in corrosive petroleum refining environments. Environmental cracking is a broad category, which the editor and authors have decided should embrace true stress corrosion cracking, hydrogen induced cracking of various kinds, and liquid metal cracking. Ian sutton, in plant design and operations second edition, 2017. Refineries and other industries were outside of mr0175s scope. The failure is brittle due to the ingress of atomic hydrogen h. Sulfide stress crackingresistant drill pipe addresses h2s. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. The first type is commonly referred to as hydrogen induced cracking hic and can occur where little or no applied or residual tensile stress exists. This affects a normally ductile material making it hard and brittle. Sulfide stress corrosion cracking ssc is a form of hydrogen embrittlement cracking which occurs when a susceptible material is exposed to a corrosive environment containing water and h2s at a critical level of applied or residual tensile stress.
477 862 302 978 813 1106 1139 9 848 111 455 298 1422 1525 989 1033 793 242 119 752 1208 1150 1300 1279 335 912 242 566 1190 936 840